Research and Development of Active Interface Electrolytic CO2 to CO in Fujian Oxygen-Reduction Modulation Institute

High-temperature electrolysis of CO2 chemicals has important research significance and application prospects in CO2 conversion and high value utilization. However, the current solid oxide electrolysis cell is derived from traditional fuel cells, and the electrolysis of CO2 polarization loss is still facing great challenges. In electrochemical systems, the interface between active components not only determines the activity of various materials but also dominates their life.

Xie Kui's group, Key Laboratory of Functional Nanostructure Design and Assembly, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, supported by key projects of the National Fund Major Research Program and the Institute of Clean Energy Innovation, Chinese Academy of Sciences, through the interface engineering strategy of redox modulation, at the nanoscale A new metal-oxide interface system can be reversibly constructed by synergistically controlling the function and interface structure of the material, and an active interface system for constructing nanometals on the surface of the porous oxide support and an inverse active interface system for constructing oxides on the surface of the porous metal are realized. The new interface system greatly enhances the interface oxygen transmission kinetics and realizes the efficient electrolysis of CO2 to CO. The results were published in "Nature Communications" (Nature Communications). The construction and modulation of the active interface system has important reference significance in the field of heterogeneous catalysis and external field coupling catalysis.

The research group has previously carried out research work on the new interface system and thermoelectric coupling catalysis of CH4 / CO2 to olefins (Nature Communications, 2019, 10, 1173; Science Advances, 2018, 4, eaar5100; Nature Communications, 2017, 8, 14785) jobs. And the long-range order of the unsaturated coordination local structure is constructed to construct a porous single crystal system, and the activation mechanism of coordination-based unsaturation and local electronic states on carbon-based molecules is clarified (Advanced Materials, 2018,180655; Materials Horizons, 2018, 5,953-960; Nature Communications, 2017, 8, 2178).

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